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Skype is the most popular app for voice and video calling.
In the mobile market, Skype has since long been dethroned by Whats App and Viber, but it still remains the most prominent tool for free communication on computers.
More » Google Hangouts is great for many reasons, one being that most everyone can login right away, given that they have a Gmail account.
Note: Go to the Facebook Help Center if you need help using Facebook's video chat feature through or the mobile Messenger app.
More » on Apple's operating system and devices, and only to other Facetime users.
It works so much like a regular phone that it should be one of the easier apps to use from this list. You can download the app on other devices like Android and i OS, but those devices can only use the text and voice calling features.
More » The most popular social network lets you communicate over not only text but also video, and it can even be done from within your web browser (Firefox, Chrome, and Opera).